Influence of Polyethylene Glycol and Methanol Additions on the Properties of Ball-Milled Cu4B4C Composite Powders

Authors

  • Serkan BIYIK Karadeniz Technical University

DOI:

https://doi.org/10.22399/ijcesen.317

Keywords:

Boron carbide, Copper composites, Methanol, Polyethylene glycol, Powder technology

Abstract

This study investigated the effect of different process control agent (PCA) usage on mechanical alloying behavior of boron carbide (B4C) reinforced copper (Cu) based composite powder. For this purpose, elemental Cu and B4C powders were weighed and powder specimens were prepared with respect to appropriate mass ratios (96% Cu and 4% B4C). Two different PCA additives, namely polyethylene glycol (PEG) and methanol, were also used to prepare powder samples. The amount of PCA was kept constant at 5wt.% for both specimen. These prepared powder samples were then milled using a planetary type ball-mill. After specified milling periods, milling runs were interrupted and powder samples were extracted from the milling vials for further powder characterization including powder morphology using scanning electron microscopy (SEM) and average particle size (APS) via laser diffraction analysis (Mastersizer). Accordingly, after the completion of milling runs, namely 15 hours of ball-milling, methanol addition was found much more effective at reducing particle sizes than PEG. Final APS values for powder specimens having PEG and methanol as PCAs were determined to be 8.237 and 4.101 microns, respectively.

References

ALMisned, G., Günoğlu, K., Özkavak, H. V., Sen Baykal, D., Tekin, H., Karpuz, N. et al. (2023). An investigation on gamma-ray and neutron attenuation properties of multi-layered Al/B4C composite. Materials Today Communications. 36:106813. DOI:10.1016/j.mtcomm.2023.106813 DOI: https://doi.org/10.1016/j.mtcomm.2023.106813

Biyik, S. (2019). Effect of cubic and hexagonal boron nitride additions on the synthesis of Ag–SnO2 electrical contact material. Journal of Nanoelectronics and Optoelectronics. 14(7):1010-1015. DOI:10.1166/jno.2019.2592 DOI: https://doi.org/10.1166/jno.2019.2592

Kartal, İ. & Selimoğlu, H. (2023). Usability of pine sawdust and calcite together as filler in polyester composites. International Journal of Computational and Experimental Science and Engineering. 9(3):267-273. DOI:10.22399/ijcesen.1335325

Malidarre, R. B., Akkurt, İ., Gunoglu, K. & Akyıldırım, H. (2021). Fast neutrons shielding properties for HAP-Fe2O3 composite materials. International Journal of Computational and Experimental Science and Engineering. 7(3):143-145. DOI:10.22399/ijcesen.1012039 DOI: https://doi.org/10.22399/ijcesen.1012039

Pang, Y., Miao, X., Zhang, Q., Chen, Z., Hao, L., Zhong, J. et al. (2023). Effect of graphene on the high-energy arc erosion performance of the W-Cu composite. Vacuum. 210:111827. DOI:10.1016/j.vacuum.2023.111827 DOI: https://doi.org/10.1016/j.vacuum.2023.111827

Demirel, H., Güneş, A. & Şahin, Ö. S. (2019). Recycling and characterization of metallic chips using powder metallurgy. International Journal of Computational and Experimental Science and Engineering. 5(3):151-153. DOI:10.22399/ijcesen.369722 DOI: https://doi.org/10.22399/ijcesen.369722

Güneş, A., Gülbahçe, E., Salur, E., Aslan, A. & Şahin, Ö. S. (2019). Vibration behavior of composite materials produced by waste metal recycling. International Journal of Computational and Experimental Science and Engineering. 5(3):139-141. DOI:10.22399/ijcesen.374400 DOI: https://doi.org/10.22399/ijcesen.374400

Oruncak, B. (2023). Computation of neutron coefficients for B2O3 reinforced composite. International Journal of Computational and Experimental Science and Engineering. 9(2):50-53. DOI:10.22399/ijcesen.1290497 DOI: https://doi.org/10.22399/ijcesen.1290497

Guler, O., Varol, T., Alver, U. & Biyik, S. (2021). The wear and arc erosion behavior of novel copper based functionally graded electrical contact materials fabricated by hot pressing assisted electroless plating. Advanced Powder Technology. 32(8):2873-2890. DOI: 10.1016/j.apt.2021.05.053 DOI: https://doi.org/10.1016/j.apt.2021.05.053

Demir, E. & Sayer, M. (2017). Investigation of notch effect on vibration behavior of filled and unfilled composite beam. International Journal of Computational and Experimental Science and Engineering. 3(1):33-37. DOI:10.22399/ijcesen.323868 DOI: https://doi.org/10.22399/ijcesen.323868

Kartal, İ., Kasap, K. & Demirer, H. (2023). Investigation of mechanical properties of domestic black tea waste filled vinylester composites. International Journal of Computational and Experimental Science and Engineering. 9(4):435-440. DOI:10.22399/ijcesen.1335309

Yener, T. & Zeytin, S. (2017). Synthesis of Ti-TiAl3 composite by resistive sintering. International Journal of Computational and Experimental Science and Engineering. 3(2):41-43.

Evcin, A., Güney, H. & Bezir, N. Ç. (2021). Sol-gel preparation of silan based titania hybrid composite thin film. International Journal of Computational and Experimental Science and Engineering. 7(1):25-28. DOI:10.22399/ijcesen.727277 DOI: https://doi.org/10.22399/ijcesen.727304

Kartal, İ. & Selimoğlu, H. (2023). Investigation of the mechanical behavior of recycled polypropylene-based composite materials filled with waste cotton and pine sawdust. International Journal of Computational and Experimental Science and Engineering. 9(4):412-418. DOI:10.22399/ijcesen.1332982

Çilli, A., Beken, M. & Kurt, N. (2022). Determination of theoretical fracture criteria of layered elastic composite material by ANFIS method from artificial intelligence. International Journal of Computational and Experimental Science and Engineering. 8(2):32-39. DOI:10.22399/ijcesen.1077328 DOI: https://doi.org/10.22399/ijcesen.1077328

Suryanarayana, C., Al-Joubori, A. A. & Wang, Z. (2022). Nanostructured materials and nanocomposites by mechanical alloying: an overview. Metals and Materials International. 28(1):41-53. DOI:10.1007/s12540-021-00998-5 DOI: https://doi.org/10.1007/s12540-021-00998-5

Biyik, S. (2024). Effect of Y2O3 addition and milling time on the synthesis of nanocrystalline Ag–ZnO composite powder via mechanical alloying. Journal of Radiation Research and Applied Sciences. 17(2):100867. DOI: 10.1016/j.jrras.2024.100867 DOI: https://doi.org/10.1016/j.jrras.2024.100867

Guo, X., Song, K., Duan, K., Luo, Q., Li, K. & Miao, X. (2024). Microstructure and arc erosion behavior of WC/CuCr30 composites based on nano-Cr precipitation. Vacuum. 222:112954. DOI:10.1016/j.vacuum.2023.112954 DOI: https://doi.org/10.1016/j.vacuum.2023.112954

Biyik, S. (2017). Characterization of nanocrystalline Cu25Mo electrical contact material synthesized via ball milling. Acta Physica Polonica A. 132(3):886-888. DOI:10.1016/j.anucene.2009.09.005 DOI: https://doi.org/10.12693/APhysPolA.132.886

Biyik, S. & Aydin, M. (2017). Optimization of mechanical alloying parameters of Cu25W electrical contact material. ACTA Physica Polonica A. 132(3):909-912. DOI:10.12693/APhysPolA.132.909 DOI: https://doi.org/10.12693/APhysPolA.132.909

Biyik, S. & Aydin, M. (2015). The effect of milling speed on particle size and morphology of Cu25W composite powder. ACTA Physica Polonica A. 127(4):1255-1260. DOI: 10.12693/APhysPolA.127.1255 DOI: https://doi.org/10.12693/APhysPolA.127.1255

Biyik, S. (2018). Effect of polyethylene glycol on the mechanical alloying behavior of Cu-W electrical contact material. ACTA Physica Polonica A. 134(1):208-212. DOI: 10.12693/APhysPolA.134.208 DOI: https://doi.org/10.12693/APhysPolA.134.208

Biyik, S. (2019). Influence of type of process control agent on the synthesis of Ag8ZnO composite powder. ACTA Physica Polonica A. 135(4):778-781. DOI: 10.12693/APhysPolA.135.778 DOI: https://doi.org/10.12693/APhysPolA.135.778

Tunç, S. A., Çanakçı, A., Karabacak, A. H., Çelebi, M. & Türkmen, M. (2024). Effect of different PCA types on morphology, physical, thermal and mechanical properties of AA2024-B4C composites. Powder Technology. 434:119373. DOI:10.1016/j.powtec.2024.119373 DOI: https://doi.org/10.1016/j.powtec.2024.119373

Biyik, S. (2019). Investigation of the effect of different process control agents on the production of Cu25W composite powder via ball milling technique. Gümüşhane Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 9(2):222-228. DOI:10.17714/gumusfenbil.426995 DOI: https://doi.org/10.17714/gumusfenbil.426995

(in Turkish with English abstract)

Li, H., Zhou, M., Tian, B., Zhang, Y., Ma, Z., Li, X. et al. (2024). Microstructure and electrical contact properties of Al2O3-Cu/(Cr, Zr) composites. Materials Today Communications. 38:107747. DOI:10.1016/j.mtcomm.2023.107747 DOI: https://doi.org/10.1016/j.mtcomm.2023.107747

Biyik, S., Arslan, F. & Aydin, M. (2015). Arc-erosion behavior of boric oxide-reinforced silver-based electrical contact materials produced by mechanical alloying. Journal of Electronic Materials. 44(1):457-466. DOI: 10.1007/s11664-014-3399-4 DOI: https://doi.org/10.1007/s11664-014-3399-4

Biyik, S. & Aydin, M. (2017). Fabrication and arc-erosion behavior of Ag8SnO2 electrical contact materials under inductive loads. ACTA Physica Polonica A. 131(3):339-342. DOI: 10.12693/APhysPolA.131.339 DOI: https://doi.org/10.12693/APhysPolA.131.339

Kiryukhantsev-Korneev, P., Sytchenko, A., Moskovskikh, D., Kuskov, K., Volkova, L., Poliakov, M. et al. (2023). Hard wear-resistant Ti-Si-C coatings for Cu-Cr electrical contacts. Materials. 16:936. DOI:10.3390/ma16030936 DOI: https://doi.org/10.3390/ma16030936

Biyik, S. (2018). Effect of reinforcement ratio on physical and mechanical properties of Cu-W composites synthesized by ball milling. Materials Focus. 7(4):535-541. DOI:10.1166/mat.2018.1513 DOI: https://doi.org/10.1166/mat.2018.1513

Zhou, Z., Yang, Z., Wu, Y. & Liu, L. (2024). Erosion characteristics of WCu/Ti3SiC2 electrical contact materials by arc discharge in various ambient atmospheres. Vacuum. 220:112821. DOI:10.1016/j.vacuum.2023.112821 DOI: https://doi.org/10.1016/j.vacuum.2023.112821

Huang, W., Yu, H., Wang, L., Wu, X., Ouyang, C., Zhang, Y. et al. (2023). State of the art and prospects in sliver- and copper-matrix composite electrical contact materials. Materials Today Communications. 37:107256. DOI:10.1016/j.mtcomm.2023.107256 DOI: https://doi.org/10.1016/j.mtcomm.2023.107256

Ma, Z., Zhou, M., Tian, B., Zhang, Y., Li, H., Li, X. et al. (2024). Nano-Y2O3 effects on the electrical contact properties of Al2O3-Cu/35Cr3TiB2 composites. Materials Characterization. 207:113474. DOI:10.1016/j.matchar.2023.113474 DOI: https://doi.org/10.1016/j.matchar.2023.113474

Li, Z., Wang, X., Li, D., Qiu, Y. & Fei, Y. (2024). Simultaneously enhanced mechanical and electrical performance of Cu-10wt.%Mo contact material by the addition of graphite. Diamond and Related Materials. 141:110720. DOI:10.1016/j.diamond.2023.110720 DOI: https://doi.org/10.1016/j.diamond.2023.110720

Liu, S., Lu, P., Guan, J., Zhang, F. & Hong, J. (2023). A new TiBN conductive ceramic powder and its application in copper-based electrical contact materials. Ceramics International. 49:26084-26094. DOI:10.1016/j.ceramint.2023.05.163 DOI: https://doi.org/10.1016/j.ceramint.2023.05.163

Liang, S., Li, Y., Zhang, Y., Zhou, M., Liu, S., Li, X. et al. (2023). Mechanical and electrical properties of Cu30Cr0.2Zr composites enhanced by CeO2/GO. Journal of Alloys and Compounds. 934:167759. DOI:10.1016/j.jallcom.2022.167759 DOI: https://doi.org/10.1016/j.jallcom.2022.167759

Varol, T., Çanakçı, A., Özşahin, Ş., Beder, M. & Akçay, S. B. (2024). Prediction of effect of fabrication parameters on the properties of B4C ceramic particle reinforced AA2024 matrix nanocomposites using neural networks. Materials Today Communications. 39:109279. DOI:10.1016/j.mtcomm.2024.109279 DOI: https://doi.org/10.1016/j.mtcomm.2024.109279

Akçay, S. B., Kocaman, M., Güler, O., Ömür, F. D., Varol, T., Aslan, M. et al. (2024). Effect of the Ag coated ABS granules and hot-pressing temperature on the microstructure evolution and properties of novel Ag/ABS composites. Surfaces and Interfaces. 51:104600. DOI:10.1016/j.surfin.2024.104600 DOI: https://doi.org/10.1016/j.surfin.2024.104600

Akçay, S. B., Kocaman, M., Çelebi, M., Güler, O. & Varol, T. (2024). Surface modification for improving interfacial, mechanical and thermal performance characteristics in epoxy composites: Electroless nickel enhancement of dendritic copper particle-reinforced epoxy. Surface and Coatings Technology. 478:130417. DOI:10.1016/j.surfcoat.2024.130417 DOI: https://doi.org/10.1016/j.surfcoat.2024.130417

Yalçın, E. D., Çanakçı, A., Çuvalcı, H., Varol, T. & Karabacak, A. H. (2023). The effect of boron nitride (h-BN) and silicon carbide (SiC) on the microstructure and wear behavior of ZA40/SiC/h-BN hybrid composites processed by hot pressing. Kovove Materialy-Metallic Materials. 61(4): 257-266. DOI: 10.31577/km.2023.4.257 DOI: https://doi.org/10.31577/km.2023.4.257

Çevik, Z. A., Karabacak, A. H., Kök, M., Çanakçı, A., Kumar, S. S. & Varol, T. (2021). The effect of machining processes on the physical and surface characteristics of AA2024-B4C-SiC hybrid nanocomposites fabricated by hot pressing method. Journal of Composite Materials. 55(19):2657-2671. DOI:10.1177/0021998321996419 DOI: https://doi.org/10.1177/0021998321996419

Güler, O., Varol, T., Alver, Ü., Kaya, G. & Yıldız, F. (2021). Microstructure and wear characterization of Al2O3 reinforced silver coated copper matrix composites by electroless plating and hot pressing methods. Materials Today Communications. 27:102205. DOI:10.1016/j.mtcomm.2021.102205 DOI: https://doi.org/10.1016/j.mtcomm.2021.102205

Varol, T., Canakci, A., Ozkaya, S., & Erdemir, F. (2016). Determining the effect of flake matrix size and Al2O3 content on microstructure and mechanical properties of Al2O3 nanoparticle reinforced Al matrix composites. Particulate Science and Technology, 36(3), 312–323. https://doi.org/10.1080/02726351.2016.1248259 DOI: https://doi.org/10.1080/02726351.2016.1248259

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Published

2024-07-24

How to Cite

BIYIK, S. (2024). Influence of Polyethylene Glycol and Methanol Additions on the Properties of Ball-Milled Cu4B4C Composite Powders. International Journal of Computational and Experimental Science and Engineering, 10(3). https://doi.org/10.22399/ijcesen.317

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Research Article