The Evaluation of heavy metal contamination in soil samples in the region of Mitrovica
DOI:
https://doi.org/10.22399/ijcesen.721Keywords:
Heavy metals, Contamination factor, Pollution load index, Geo-accumulation index, Soil contaminationAbstract
The industry is crucial for the economic development of the country, but at the same time, it is one of the biggest influences on the environment. The Mitrovica region faces numerous environmental problems due to the mining-industrial processes applied in the facilities of the industrial complex "Trepça". As a result of these processes, industrial waste with a toxic composition is created, which is considered a potential polluter of soil, air, water, and vegetation in this area. The study aims to determine the concentration of heavy metals including Pb, As, Zn, Ni, Co, Cr, Cd, and Cu in soil samples. Also, the level of soil pollution with heavy metals was examined, using pollution indicators, such as contamination factor (CF), degree of contamination (Cd), modified degree of contamination (mCd), pollution load index (PLI), and geo-accumulation index (Igeo). To carry out this research, we selected 6 sampling sites in the period May - August 2024, which were characterized and evaluated as the most critical points. The concentration of heavy metals in soil samples was determined using inductively coupled plasma-optical emission spectrometry (ICP–OES Optima 2100 DV, Perkin-Elmer) by standard method US EPA 6010C. From the obtained results it was found that the level of heavy metals analyzed in this work, respectively the level of zinc (197.84 - 3456.14 mgkg-1), lead (204.75 - 3458.16 mgkg-1), and arsenic (30.76 – 634.56 mgkg-1) is relatively high and exceeds the allowed values recommended by Kosovo and European Legislation.
References
Huo, J., & Peng, Ch. (2003). Depletion of natural resources and environmental quality: Prospects of energy use, energy imports, and economic growth hindrances, Resources Policy 86;104049. DOI:10.1016/j.resourpol.2023.104049
Dagdag, O., Quadri, T. W., Haldhar, R., et al. (2023). An Overview of Heavy Metal Pollution and Control. Heavy Metals in the Environment: Management Strategies for Global Pollution, Chapter 1pp 3-24. ACS Symposium Series; American Chemical Society: Washington, DC. http://dx.doi.org/10.1021/bk-2023-1456.ch001
Tchounwou, P.B., Yedjou C.G.,& Patlolla A.K. (2012). Heavy Metals Toxicity and the Environment. (Springer Basel), EXS, 101;133–164. doi: 10.1007/978-3-7643-8340-4_6
Mitra, S., Chakraborty, A. J., Tareq, A. M., et al. (2022). Impact of heavy metals on the environment and human health: Novel therapeutic insights to counter the toxicity. Journal of King Saud University - Science, 34(3);101865. https://doi.org/10.1016/j.jksus.2022.101865
Tomczyk, P., Wdowczyk, A., Wiatkowska, B., et al. (2023). Assessment of heavy metal contamination of agricultural soils in Poland using contamination indicators. Ecological Indicators, 156;111161. https://doi.org/10.1016/j.ecolind.2023.111161
Massas, I., Kalivas D., Ehaliotis C., & Gasparatos, D. (2013). Total and available heavy metal concentrations in soils of the Thriassio plain (Greece) and assessment of soil pollution indexes. Environ Monit Assess. 185;6751–6766 http://dx.doi.org/10.1007/s10661-013-3062-1
Adriano, D.C. (2001). Trace Elements in Terrestrial Environments: Biogeochemistry, Bioavailability and Risks of Metals. 2nd Edition, Springer, New York, 867. Springer- Verlag, New York. http://dx.doi.org/10.1007/978-0-387-21510-5
Kerolli Mustafa, M., Fajković, H., Rončević, S. & Ćurković L. (2015). Assessment of metals risks from different depths of jarosite tailing waste of Trepça Zinc Industry, Kosovo based on BCR procedure. J. Geochem. Explor. 148;161–168. http://dx.doi.org/10.1016/j.gexplo.2014.09.001
Raj, K., & Das, A.P. (2023). Lead pollution: Impact on environment and human health and approach for a sustainable solution. Environmental Chemistry and Ecotoxicology, 5;79-85. https://doi.org/10.1016/j.enceco.2023.02.001
Arooj, S., Naz, Sh., Qaisar, A., Satti, S., et al. (2024). Estimation of Heavy Metals Enrichment and Geo-Accumulation Associated with Habitat Quality from Selected Wildlife Parks. Soil and Sediment Contamination: An International Journal 34(1);1–18.https://doi.org/10.1080/15320383.2024.2328038
Ferreira, S.L.C., da Silva Junior, J.B., Ferreira dos Santos, I. et al. (2022). Use of pollution indices and ecological risk in the assessment of contamination from chemical elements in soils and sediments – Practical aspects. Trends in Environmental Analytical Chemistry, 35. https://doi.org/10.1016/j.teac.2022.e00169
Zeqiri, L., Ukić, Š., Ćurković, L., Djokic, J., & Kerolli Mustafa, M. (2024). Distribution of Heavy Metals inSurrounding Mining Region of Kizhnica in Kosovo. Sustainability, 16(16), 6721. https://doi.org/10.3390/su16166721
Zabërgja Ferati, F., Kerolli Mustafa, M., & Abazaj. F. (2021) Heavy Metal Contamination and Accumulation in Soil and Plant from Mining Area of Mitrovica, Kosovo. Bulletin of Environmental Contamination and Toxicology, 107:537–543 https://doi.org/10.1007/s00128-021-03223-6
Zabërgja F Zabërgja Ferati, F., Kerolli Mustafa, M., & Abazaj. F. (2022). Effects of Metal Toxicity on the Growth and Photosynthetic Pigment Contents of Salix purpurea in Mitrovica, Kosovo, Kem. Ind. 71 (3-4), 123−130. https://doi.org/10.15255/KUI.2021.022
ISO 11464 (2006), Soil quality — Pretreatment of samples for physico-chemical analysis
US Environmental Protection Agency (1996). Method 3052. Microwave assisted acid digestion of siliceous and organically based matrices
US Environmental Protection Agency 6010C (2007). Inductively coupled plasma—atomic emission spectrometry.
ISO 10390 (2005), Soil quality - Determination of pH.
Min, X., Xie, X., Chai, L., Liang, Y., Li, M., & Ke, Y. (2013). Environmental availability and ecological risk assessment of heavy metals in zinc leaching residue. Transactions of the Nonferrous Metals Society of China, 23, 208–218. https://doi.org/10.1016/S1003-6326(13)62448-6
Republic of Kosovo/Ministry of Environment and Spatial Planning, Administrative Instruction No. 11/2018, On limited values of emissions of polluted materials into soil.
Müller, G. (1969). Index of geo-accumulation in the sediments of the Rhine River. Journal of Geology, 2, 108-118.
Özkan, E. Y. (2012). A new assessment of heavy metal contaminations in an eutrophicated bay (Inner Izmir Bay, Turkey). Turkish Journal of Fisheries and Aquatic Sciences, 12, 135–147. http://dx.doi.org/10.4194/1303-2712-v12_1_16
Håkanson, L. (1980). An ecological risk index for aquatic pollution control—a sedimentological approach. Water Research, 14;975–1001. http://dx.doi.org/10.1016/0043-1354(80)90143-8
Abrahim, G. M. S., & Parker, R. J. (2008). Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki Estuary, Auckland, New Zealand. Environmental Monitoring and Assessment, 136, 227–238. http://dx.doi.org/10.1007/s10661-007-9678-2
Tomlinson, D. C., Wilson, J. G., Harris, C. R., & Jeffrey, D. W. (1980). Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoland Marine Research, 33(1), 566–575. http://dx.doi.org/10.1007/BF02414780
Chinmaya, K. S. (2024). Environmental pollution indices: a review on concentration of heavy metals in air, water, and soil near industrialization and urbanisation, Discover Environment, 2,5 http://dx.doi.org/10.1007/s44274-024-00030-8
Council Directive 86/278/EEC. (1986). On the protection of the environment, and in particular of the soil. https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:31986L0278
Alloway, B.J. (2013). Heavy metals in soils, Trase Metals and Metalloids in Soils and their Bioavailability, 3nd edition. Springer, DOI:10.1007/978-94-007-4470-7
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 International Journal of Computational and Experimental Science and Engineering

This work is licensed under a Creative Commons Attribution 4.0 International License.